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Issue 85, 2015
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Hydrophobic pillared square grids for selective removal of CO2 from simulated flue gas

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Abstract

Capture of CO2 from flue gas is considered to be a feasible approach to mitigate the effects of anthropogenic emission of CO2. Herein we report that an isostructural family of metal organic materials (MOMs) of general formula [M(linker)2(pillar)], linker = pyrazine, pillar = hexaflourosilicate and M = Zn, Cu, Ni and Co exhibits highly selective removal of CO2 from dry and wet simulated flue gas. Two members of the family, M = Ni and Co, SIFSIX-3-Ni and SIFSIX-3-Co, respectively, are reported for the first time and compared with the previously reported Zn and Cu analogs.

Graphical abstract: Hydrophobic pillared square grids for selective removal of CO2 from simulated flue gas

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Article information


Submitted
06 Aug 2015
Accepted
28 Aug 2015
First published
01 Sep 2015

Chem. Commun., 2015,51, 15530-15533
Article type
Communication

Hydrophobic pillared square grids for selective removal of CO2 from simulated flue gas

S. K. Elsaidi, M. H. Mohamed, H. T. Schaef, A. Kumar, M. Lusi, T. Pham, K. A. Forrest, B. Space, W. Xu, G. J. Halder, J. Liu, M. J. Zaworotko and P. K. Thallapally, Chem. Commun., 2015, 51, 15530
DOI: 10.1039/C5CC06577A

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