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Abstract | Cited by

By using the supermolecular building block (SBB) strategy, a polyhedron-based metal–organic framework (PMOF), which features three types of cages with multiple sizes and shapes, has been synthesized. It exhibits high performance for CO2 capture (170 cm3 g−1 at 273 K under 1 bar) and selectivity of CO2/CH4 (9.4) and C3H8/CH4 (271.5).

Graphical abstract: A polyhedral metal–organic framework based on the supermolecular building block strategy exhibiting high performance for carbon dioxide capture and separation of light hydrocarbons

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