Issue 96, 2015
From the journal:

Chemical Communications

Substitution of Co2+ ions into CdS-based molecular clusters†

Swamy Pittala,a   Michael J. Mortelliti,a   Fumitoshi Katoa  and  Kevin R. Kittilstved*a  

* Corresponding authors

a Department of Chemistry, University of Massachusetts, 122 Lederle GRC, 710 N Pleasant St, Amherst, MA 01003, USA
E-mail: kittilstved@chem.umass.edu

Abstract

We report on the metal ion exchange between Co2+ and CdS-based molecular clusters. These studies demonstrate that exchange into the smaller [Cd4(SPh)10]2− clusters is facile compared to the larger [Cd10S4(SPh)16]4− and [Cd17S4(SPh)28]2− clusters. This trend correlates with the rate of benzenethiolate interconversion and μ-S2− and μ-SPh− content among the clusters.

Graphical abstract: Substitution of Co2+ ions into CdS-based molecular clusters

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Article information

DOI
https://doi.org/10.1039/C5CC06138E
Article type
Communication
Submitted
22 Jul 2015
Accepted
05 Oct 2015
First published
05 Oct 2015

Chem. Commun., 2015,51, 17096-17099

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Substitution of Co2+ ions into CdS-based molecular clusters

S. Pittala, M. J. Mortelliti, F. Kato and K. R. Kittilstved, Chem. Commun., 2015, 51, 17096 DOI: 10.1039/C5CC06138E

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