A unique TfOH-catalyzed domino cycloisomerization/hydrolytic defluorination reaction of easily available n-perfluoroalkyl allenones in the presence of H2O providing furanyl perfluoroalkyl ketones has been developed. The 18O-labelling experiments confirmed that the oxygen atom of the carbonyl group in the final products originates from water.
C. Xue, X. Huang, S. Wu, J. Zhou, J. Dai, C. Fu and S. Ma, Chem. Commun., 2015, 51, 17112 DOI: 10.1039/C5CC06111C
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