Issue 71, 2015
From the journal:

Chemical Communications

Reaction of N-heterocyclic carbenes with chalcones leading to the synthesis of deoxy-Breslow intermediates in their oxidized form†

Anup Bhunia,a   Shridhar Thorat,b   Rajesh G. Gonnadeb  and  Akkattu T. Biju*a  

* Corresponding authors

a Organic Chemistry Division, CSIR-National Chemical Laboratory (CSIR-NCL), Dr. Homi Bhabha Road, Pune-411008, India
E-mail: at.biju@ncl.res.in
Fax: +91-20-25902629
Tel: +91-20-25902441

b Centre for Materials Characterization, CSIR-National Chemical Laboratory (CSIR-NCL), Dr. Homi Bhabha Road, Pune-411008, India

Abstract

The synthesis of deoxy-Breslow intermediates in their oxidized form has been developed via the reaction of N-heterocyclic carbenes (NHCs) with chalcones. Moreover, the initial tetrahedral adduct formed from the 1,4-addition of NHCs to chalcones is also isolated.

Graphical abstract: Reaction of N-heterocyclic carbenes with chalcones leading to the synthesis of deoxy-Breslow intermediates in their oxidized form

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Article information

DOI
https://doi.org/10.1039/C5CC05800G
Article type
Communication
Submitted
13 Jul 2015
Accepted
14 Jul 2015
First published
20 Jul 2015

Chem. Commun., 2015,51, 13690-13693

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Reaction of N-heterocyclic carbenes with chalcones leading to the synthesis of deoxy-Breslow intermediates in their oxidized form

A. Bhunia, S. Thorat, R. G. Gonnade and A. T. Biju, Chem. Commun., 2015, 51, 13690 DOI: 10.1039/C5CC05800G

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