Issue 75, 2015
From the journal:

Chemical Communications

Homogeneous liquid–liquid extraction of metal ions with non-fluorinated bis(2-ethylhexyl)phosphate ionic liquids having a lower critical solution temperature in combination with water†

Daphne Depuydt,a   Liwang Liu,b   Christ Glorieux,b   Wim Dehaena  and  Koen Binnemans*a  

* Corresponding authors

a KU Leuven, Department of Chemistry, Celestijnenlaan 200F, P.O. Box 2404, B-3001 Heverlee, Belgium
E-mail: Koen.Binnemans@chem.kuleuven.be

b KU Leuven, Department of Physics and Astronomy, Celestijnenlaan 200D, P.O. Box 2416, B-3001 Heverlee, Belgium

Abstract

Ionic liquids with an ether-functionalised cation and the bis(2-ethylhexyl)phosphate anion show thermomorphic behaviour in water, with a lower critical solution temperature. These ionic liquids are useful for homogeneous liquid–liquid extraction of first-row (3d) transition metals.

Graphical abstract: Homogeneous liquid–liquid extraction of metal ions with non-fluorinated bis(2-ethylhexyl)phosphate ionic liquids having a lower critical solution temperature in combination with water

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Article information

DOI
https://doi.org/10.1039/C5CC05649G
Article type
Communication
Submitted
08 Jul 2015
Accepted
30 Jul 2015
First published
31 Jul 2015

Chem. Commun., 2015,51, 14183-14186

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Homogeneous liquid–liquid extraction of metal ions with non-fluorinated bis(2-ethylhexyl)phosphate ionic liquids having a lower critical solution temperature in combination with water

D. Depuydt, L. Liu, C. Glorieux, W. Dehaen and K. Binnemans, Chem. Commun., 2015, 51, 14183 DOI: 10.1039/C5CC05649G

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