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Issue 65, 2015
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Light-driven nitrile imine-mediated tetrazole–ene cycloaddition as a versatile platform for fullerene conjugation

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Abstract

An efficient methodology for modular fullerene functionalization via the photo-induced nitrile imine-mediated tetrazole–ene cycloaddition (NITEC) is introduced. The versatility and platform character of the method is illustrated by the light-driven reaction of fullerenes with small molecule, polymeric and surface-immobilized tetrazoles. The efficient fullerene conjugation is evidenced via mass spectrometric techniques.

Graphical abstract: Light-driven nitrile imine-mediated tetrazole–ene cycloaddition as a versatile platform for fullerene conjugation

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Article information


Submitted
06 Jul 2015
Accepted
09 Jul 2015
First published
09 Jul 2015

Chem. Commun., 2015,51, 13000-13003
Article type
Communication

Light-driven nitrile imine-mediated tetrazole–ene cycloaddition as a versatile platform for fullerene conjugation

Y. Sugawara, N. Jasinski, M. Kaupp, A. Welle, N. Zydziak, E. Blasco and C. Barner-Kowollik, Chem. Commun., 2015, 51, 13000
DOI: 10.1039/C5CC05507E

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