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Issue 87, 2015
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Bis(mandelato)borate: an effective, inexpensive spiroborate anion for chiral resolution

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Abstract

Bis(mandelato)borate [B(Man)2] (R- or S-) anions are simply prepared and appear widely effective for resolution of racemic cations. Three examples demonstrate their scope; the alkaloid tetrahydropalmatine (THP), 1,2-diaminopropane (1,2-dap) and the metal–organic complex [Co(phen)3]3+ are readily resolved, either by a facile one-pot procedure, or via counter-ion metathesis.

Graphical abstract: Bis(mandelato)borate: an effective, inexpensive spiroborate anion for chiral resolution

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Publication details

The article was received on 16 Jun 2015, accepted on 28 Aug 2015 and first published on 02 Sep 2015


Article type: Communication
DOI: 10.1039/C5CC04977F
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Citation: Chem. Commun., 2015,51, 15760-15763

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    Bis(mandelato)borate: an effective, inexpensive spiroborate anion for chiral resolution

    L. W-Y. Wong, J. W-H. Kan, T. Nguyen, H. H-Y. Sung, D. Li, A. S-F. Au-Yeung, R. Sharma, Z. Lin and I. D. Williams, Chem. Commun., 2015, 51, 15760
    DOI: 10.1039/C5CC04977F

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