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Issue 73, 2015

Low-valent iron: an Fe(i) ate compound as a building block for a linear trinuclear Fe cluster

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Abstract

A low-valent trinuclear iron complex with an unusual linear Fe(I)–Fe(II)–Fe(I) unit is presented. It is accessed in a rational approach using a salt metathesis reaction between a new anionic Fe(I) containing heterocycle and FeCl2. Its electronic structure was studied by single crystal XRD analysis, EPR and Mössbauer spectroscopy, and magnetic susceptibility measurements.

Graphical abstract: Low-valent iron: an Fe(i) ate compound as a building block for a linear trinuclear Fe cluster

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Article information


Submitted
14 Jun 2015
Accepted
22 Jul 2015
First published
23 Jul 2015

Chem. Commun., 2015,51, 13890-13893
Article type
Communication

Low-valent iron: an Fe(I) ate compound as a building block for a linear trinuclear Fe cluster

C. Lichtenberg, L. Viciu, M. Vogt, R. E. Rodríguez-Lugo, M. Adelhardt, J. Sutter, M. M. Khusniyarov, K. Meyer, B. de Bruin, E. Bill and H. Grützmacher, Chem. Commun., 2015, 51, 13890 DOI: 10.1039/C5CC04908C

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