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Issue 70, 2015
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A novel visible light mediated radical cyclization of enol lactones: a concise method for fluorinated polycyclic lactone scaffolds

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Abstract

A novel visible light mediated radical cyclization of enol lactones with difluoroacyl arenes is presented. The reaction experienced a tandem radical cyclization and tolerated a wide range of substrates, resulting in fluorinated γ-butyrolactones in good chemical yield and with excellent diastereoselectivity.

Graphical abstract: A novel visible light mediated radical cyclization of enol lactones: a concise method for fluorinated polycyclic lactone scaffolds

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Supplementary files

Article information


Submitted
16 Jun 2015
Accepted
16 Jul 2015
First published
16 Jul 2015

Chem. Commun., 2015,51, 13508-13510
Article type
Communication
Author version available

A novel visible light mediated radical cyclization of enol lactones: a concise method for fluorinated polycyclic lactone scaffolds

C. Qu, P. Xu, W. Ma, Y. Cheng and C. Zhu, Chem. Commun., 2015, 51, 13508
DOI: 10.1039/C5CC04881H

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