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Issue 76, 2015
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Reversible stimulus-responsive Cu(i) iodide pyridine coordination polymer

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Abstract

We present a structurally flexible copper–iodide–pyridine-based coordination polymer showing drastic variations in its electrical conductivity driven by temperature and sorption of acetic acid molecules. The dramatic effect on the electrical conductivity enables the fabrication of a simple and robust device for gas detection. X-ray diffraction studies and DFT calculations allow the rationalisation of these observations.

Graphical abstract: Reversible stimulus-responsive Cu(i) iodide pyridine coordination polymer

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Supplementary files

Article information


Submitted
09 Jun 2015
Accepted
30 Jul 2015
First published
31 Jul 2015

Chem. Commun., 2015,51, 14306-14309
Article type
Communication
Author version available

Reversible stimulus-responsive Cu(I) iodide pyridine coordination polymer

P. Amo-Ochoa, K. Hassanein, C. J. Gómez-García, S. Benmansour, J. Perles, O. Castillo, J. I. Martínez, P. Ocón and F. Zamora, Chem. Commun., 2015, 51, 14306
DOI: 10.1039/C5CC04746C

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