Accessing heavy allyl-analogous [(TerN)2E]− (E = Sb, Bi) ions and their reactivity towards ECl3

Alexander Hinz; Axel Schulz; Alexander Villinger

doi:10.1039/C5CC04355G

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Accessing heavy allyl-analogous [(TerN)₂E]⁻ (E = Sb, Bi) ions and their reactivity towards ECl₃†

Alexander Hinz,^a Axel Schulz*^ab and Alexander Villinger^a

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* Corresponding authors

^a Institut für Chemie, Universität Rostock, Albert-Einstein-Str. 3a, 18059 Rostock, Germany
E-mail: axel.schulz@uni-rostock.de

^b Abteilung Materialdesign, Leibniz-Institut für Katalyse e.V. an der Universität Rostock, Albert-Einstein-Str. 29a, 18059 Rostock, Germany

Abstract

The attempted preparation of the biradicaloid [E(μ-NTer)]₂ (E = Sb, Bi) yielded salts of the anion [(TerN)₂E]⁻. These heteroatom allyl analogues could be further utilized in the reaction with pnictogen(III) chlorides to form the first 1,3-dichloro-1-bisma-3-stiba-2,4-diazane [ClSb(μ-NTer)₂BiCl].

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Article information

DOI: https://doi.org/10.1039/C5CC04355G
Article type: Communication
Submitted: 27 May 2015
Accepted: 12 Jun 2015
First published: 12 Jun 2015
This article is Open Access

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Chem. Commun., 2015,51, 11437-11440

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Accessing heavy allyl-analogous [(TerN)₂E]⁻ (E = Sb, Bi) ions and their reactivity towards ECl₃

A. Hinz, A. Schulz and A. Villinger, Chem. Commun., 2015, 51, 11437 DOI: 10.1039/C5CC04355G

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. You can use material from this article in other publications without requesting further permissions from the RSC, provided that the correct acknowledgement is given.

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Chemical Communications