Jump to main content
Jump to site search

Issue 57, 2015
Previous Article Next Article

Accessing heavy allyl-analogous [(TerN)2E] (E = Sb, Bi) ions and their reactivity towards ECl3

Author affiliations

Abstract

The attempted preparation of the biradicaloid [E(μ-NTer)]2 (E = Sb, Bi) yielded salts of the anion [(TerN)2E]. These heteroatom allyl analogues could be further utilized in the reaction with pnictogen(III) chlorides to form the first 1,3-dichloro-1-bisma-3-stiba-2,4-diazane [ClSb(μ-NTer)2BiCl].

Graphical abstract: Accessing heavy allyl-analogous [(TerN)2E]− (E = Sb, Bi) ions and their reactivity towards ECl3

Back to tab navigation

Supplementary files

Publication details

The article was received on 27 May 2015, accepted on 12 Jun 2015 and first published on 12 Jun 2015


Article type: Communication
DOI: 10.1039/C5CC04355G
Citation: Chem. Commun., 2015,51, 11437-11440
  • Open access: Creative Commons BY license
  •   Request permissions

    Accessing heavy allyl-analogous [(TerN)2E] (E = Sb, Bi) ions and their reactivity towards ECl3

    A. Hinz, A. Schulz and A. Villinger, Chem. Commun., 2015, 51, 11437
    DOI: 10.1039/C5CC04355G

    This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Material from this article can be used in other publications provided that the correct acknowledgement is given with the reproduced material.

    Reproduced material should be attributed as follows:

    • For reproduction of material from NJC:
      [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the Centre National de la Recherche Scientifique (CNRS) and the RSC.
    • For reproduction of material from PCCP:
      [Original citation] - Published by the PCCP Owner Societies.
    • For reproduction of material from PPS:
      [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the European Society for Photobiology, the European Photochemistry Association, and RSC.
    • For reproduction of material from all other RSC journals:
      [Original citation] - Published by The Royal Society of Chemistry.

    Information about reproducing material from RSC articles with different licences is available on our Permission Requests page.

Search articles by author

Spotlight

Advertisements