The effects of the addition of small amount of Zr (less than 2 at%) to the fcc phase of the Pd–Cu hydrogen separation alloy were investigated. Hydrogen flux variations in Pd–Cu and Pd–Cu–Zr alloys in the presence of 1000 ppm H2S + H2 feed gas showed a marked effect of Zr addition in improving the resistance to sulphur poisoning.
S. Nayebossadri, J. D. Speight and D. . Book, Chem. Commun., 2015, 51, 15842 DOI: 10.1039/C5CC04327A
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