Issue 56, 2015
From the journal:

Chemical Communications

Pressure-dependent helix inversion of poly(quinoxaline-2,3-diyl)s containing chiral side chains in non-aqueous solvents†

Yuuya Nagata,*a   Ryohei Takedaa  and  Michinori Suginome*ab  

* Corresponding authors

a Department of Synthetic Chemistry and Biological Chemistry, Graduate School of Engineering, Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan
E-mail: suginome@sbchem.kyoto-u.ac.jp

b JST, CREST (CREST, “Development of High-performance Nanostructures for Process Integration” and “Establishment of Molecular Technology towards the Creation of New Function” Area), Kyoto University, Katsura, Nishikyo-ku, Kyoto 615-8510, Japan

Abstract

Poly(quinoxaline-2,3-diyl)s with chiral (S)-2-butoxymethyl side chains dissolved in 1,2-dichloroethane experience a reversible pressure-dependent helix inversion from P- to M-helical structures between 0.1 MPa and 200 MPa.

Graphical abstract: Pressure-dependent helix inversion of poly(quinoxaline-2,3-diyl)s containing chiral side chains in non-aqueous solvents

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Article information

DOI
https://doi.org/10.1039/C5CC04255K
Article type
Communication
Submitted
23 May 2015
Accepted
03 Jun 2015
First published
03 Jun 2015
This article is Open Access
Creative Commons BY license

Chem. Commun., 2015,51, 11182-11185

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Pressure-dependent helix inversion of poly(quinoxaline-2,3-diyl)s containing chiral side chains in non-aqueous solvents

Y. Nagata, R. Takeda and M. Suginome, Chem. Commun., 2015, 51, 11182 DOI: 10.1039/C5CC04255K

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