Issue 57, 2015
From the journal:

Chemical Communications

Iridium-catalyzed regioselective decarboxylative allylation of β-ketoacids: efficient construction of γ,δ-unsaturated ketones†

Shu-Jie Chen,a   Guo-Ping Lua  and  Chun Cai*a  

* Corresponding authors

a School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, P. R. China
E-mail: c.cai@mail.njust.edu.cn
Fax: +86-25-8431-5030
Tel: +86-25-8431-5514

Abstract

A highly regioselective protocol for the direct synthesis of γ,δ-unsaturated ketones from β-ketoacids and allylic alcohols was proposed and accomplished relying on the combination of [Ir(cod)Cl]2 and 10-camphorsulfonic acid via decarboxylative allylation.

Graphical abstract: Iridium-catalyzed regioselective decarboxylative allylation of β-ketoacids: efficient construction of γ,δ-unsaturated ketones

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Article information

DOI
https://doi.org/10.1039/C5CC03591K
Article type
Communication
Submitted
30 Apr 2015
Accepted
10 Jun 2015
First published
10 Jun 2015

Chem. Commun., 2015,51, 11512-11514

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Iridium-catalyzed regioselective decarboxylative allylation of β-ketoacids: efficient construction of γ,δ-unsaturated ketones

S. Chen, G. Lu and C. Cai, Chem. Commun., 2015, 51, 11512 DOI: 10.1039/C5CC03591K

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