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Issue 49, 2015
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Towards multifunctional MOFs – transforming a side reaction into a post-synthetic protection/deprotection method

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Abstract

The contaminant commonly found in the important amino-substituted metal–organic framework UiO-66-NH2 has been shown to arise from partial formylation during the synthesis in DMF. Mild conditions have now been developed for both post-synthetic deformylation and near-complete formylation, offering a new post-synthetic protection–deprotection method for the synthesis of multifunctional MOFs.

Graphical abstract: Towards multifunctional MOFs – transforming a side reaction into a post-synthetic protection/deprotection method

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Article information


Submitted
26 Apr 2015
Accepted
11 May 2015
First published
12 May 2015

Chem. Commun., 2015,51, 10030-10033
Article type
Communication
Author version available

Towards multifunctional MOFs – transforming a side reaction into a post-synthetic protection/deprotection method

K. M. Zwoliński, P. Nowak and M. J. Chmielewski, Chem. Commun., 2015, 51, 10030
DOI: 10.1039/C5CC03469H

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