An efficient Lewis acid-assisted, iron-catalyzed amination of alcohols using borrowing hydrogen methodology was developed. In particular, silver fluoride was identified to be a highly effective additive to overcome the low efficiency in the amination of secondary alcohols catalyzed by Knölker's complex.
H. Pan, T. W. Ng and Y. Zhao, Chem. Commun., 2015, 51, 11907 DOI: 10.1039/C5CC03399C
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