Issue 56, 2015
From the journal:

Chemical Communications

Deoxygenative coupling of nitroarenes for the synthesis of aromatic azo compounds with CO using supported gold catalysts†

Hai-Qian Li,a   Xiang Liu,a   Qi Zhang,a   Shu-Shuang Li,a   Yong-Mei Liu,a   He-Yong Hea  and  Yong Cao*a  

* Corresponding authors

a Department of Chemistry, Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials, Collaborative Innovation Center of Chemistry for Energy Materials, Fudan University, Shanghai 200433, P. R. China
E-mail: yongcao@fudan.edu.cn
Fax: +86-21-65643774

Abstract

A facile and efficient catalytic system based on a mesostructured ceria-supported gold (Au/meso-CeO2) catalyst was developed for the synthesis of various aromatic azo compounds by the reductive coupling of the corresponding nitroaromatics, using CO as the sole deoxygenative reagent, under additive-free and mild reaction conditions.

Graphical abstract: Deoxygenative coupling of nitroarenes for the synthesis of aromatic azo compounds with CO using supported gold catalysts

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Article information

DOI
https://doi.org/10.1039/C5CC03134F
Article type
Communication
Submitted
15 Apr 2015
Accepted
29 May 2015
First published
01 Jun 2015

Chem. Commun., 2015,51, 11217-11220

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Deoxygenative coupling of nitroarenes for the synthesis of aromatic azo compounds with CO using supported gold catalysts

H. Li, X. Liu, Q. Zhang, S. Li, Y. Liu, H. He and Y. Cao, Chem. Commun., 2015, 51, 11217 DOI: 10.1039/C5CC03134F

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