Yanjun Sun, Yan Yan, Yanyan Wang, Yi Li, Jiyang Li and Jihong Yu
Chem. Commun., 2015,51, 9317-9319
DOI:
10.1039/C5CC03116H,
Communication
A new open-framework aluminophosphate Na6[(AlPO4)8(OH)6]·8H2O (JU103) has been synthesized by utilization of the organotemplate-free synthetic route in alkali metal-containing system. The as-prepared JU103 possesses two-dimensional intersecting 8-ring channels. Sodium ions and water molecules in the channels facilitates JU103 excellent proton conductivity up to 3.59 × 10−3 S cm−1 (293 K, 98% RH).