Issue 52, 2015
From the journal:

Chemical Communications

One-pot tandem catalysis over Pd@MIL-101: boosting the efficiency of nitro compound hydrogenation by coupling with ammonia borane dehydrogenation†

Qihao Yang,‡a   Yu-Zhen Chen,‡a   Zhiyong U. Wang,b   Qiang Xuc  and  Hai-Long Jiang*a  

* Corresponding authors

a Hefei National Laboratory for Physical Sciences at the Microscale, Key Laboratory of Soft Matter Chemistry, Chinese Academy of Sciences, Collaborative Innovation Center of Suzhou Nano Science and Technology, Department of Chemistry, University of Science and Technology of China, Hefei, Anhui 230026, P. R. China
E-mail: jianglab@ustc.edu.cn
Web: http://staff.ustc.edu.cn/%E2%88%BCjianglab/

b Department of Chemistry and Physics, Troy University, Troy, AL 36082, USA

c National Institute of Advanced Industrial Science and Technology (AIST), Ikeda, Osaka 563-8577, Japan

Abstract

The hydrogenation efficiency of nitro compounds was found to be greatly boosted by coupling with dehydrogenation of ammonia borane. The Pd@MIL-101 with tiny Pd NPs is exceptionally efficient and recyclable in the tandem reactions and diverse nitro compounds can be selectively reduced to the corresponding amines in 1.5–5 min with quantitative yields.

Graphical abstract: One-pot tandem catalysis over Pd@MIL-101: boosting the efficiency of nitro compound hydrogenation by coupling with ammonia borane dehydrogenation

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Article information

DOI
https://doi.org/10.1039/C5CC03102H
Article type
Communication
Submitted
15 Apr 2015
Accepted
11 May 2015
First published
11 May 2015

Chem. Commun., 2015,51, 10419-10422

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One-pot tandem catalysis over Pd@MIL-101: boosting the efficiency of nitro compound hydrogenation by coupling with ammonia borane dehydrogenation

Q. Yang, Y. Chen, Z. U. Wang, Q. Xu and H. Jiang, Chem. Commun., 2015, 51, 10419 DOI: 10.1039/C5CC03102H

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