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Issue 52, 2015
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The first Fe-based Na+-ion cathode with two distinct types of polyanions: Fe3P5SiO19

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Abstract

Herein, we report the synthesis, structure, and electrochemistry of the first Na+-ion cathode with two distinct types of polyanions: Fe3P5SiO19. The Fe-based cathode has a reversible capacity of ca. 70 mA h gāˆ’1; ca. 1.7 Na+ ions per formula can be inserted/extracted at an average voltage of 2.5 V versus Na+/Na.

Graphical abstract: The first Fe-based Na+-ion cathode with two distinct types of polyanions: Fe3P5SiO19

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Publication details

The article was received on 13 Apr 2015, accepted on 15 May 2015 and first published on 15 May 2015


Article type: Communication
DOI: 10.1039/C5CC03070F
Chem. Commun., 2015,51, 10447-10450

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    The first Fe-based Na+-ion cathode with two distinct types of polyanions: Fe3P5SiO19

    W. H. Kan, A. Huq and A. Manthiram, Chem. Commun., 2015, 51, 10447
    DOI: 10.1039/C5CC03070F

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