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Issue 50, 2015
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Cationic dinuclear platinum and palladium complexes with bridging hydrogermylene and hydrido ligands

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Abstract

Hydride-abstraction reactions of hydrido(dihydrogermyl) complexes [MH(GeH2Trip)(dcpe)] [M = Pt, Pd, Trip = 9-triptycyl, dcpe = 1,2-bis(dicyclohexylphosphino)ethane] with B(C6F5)3 led to the unexpected formation of new cationic (μ-germyl)(μ-hydrido) dinuclear platinum and palladium complexes, [{M(dcpe)}2(μ-GeHTrip)(μ-H)]+.

Graphical abstract: Cationic dinuclear platinum and palladium complexes with bridging hydrogermylene and hydrido ligands

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Publication details

The article was received on 13 Apr 2015, accepted on 11 May 2015 and first published on 12 May 2015


Article type: Communication
DOI: 10.1039/C5CC03062E
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Chem. Commun., 2015,51, 10111-10114

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    Cationic dinuclear platinum and palladium complexes with bridging hydrogermylene and hydrido ligands

    N. Nakata, N. Sekizawa and A. Ishii, Chem. Commun., 2015, 51, 10111
    DOI: 10.1039/C5CC03062E

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