Jump to main content
Jump to site search
PLANNED MAINTENANCE Close the message box

Scheduled maintenance work on Wednesday 21st October 2020 from 07:00 AM to 07:00 PM (BST).

During this time our website performance may be temporarily affected. We apologise for any inconvenience this might cause and thank you for your patience.


Issue 48, 2015
Previous Article Next Article

Photoinduced electron transfer in a supramolecular triad produced by porphyrin anion-induced electron transfer from tetrathiafulvalene calix[4]pyrrole to Li+@C60

Author affiliations

Abstract

Binding of a porphyrin carboxylate anion (1) to tetrathiafulvalene calix[4]pyrrole (TTF-C4P) results in electron transfer from TTF-C4P to Li+@C60 to produce the charge-separated state (1/TTF-C4P˙+/Li+@C60˙) in benzonitrile. Upon photoexcitation of 1, photoinduced electron transfer from the triplet excited state of 1 to TTF-C4P˙+ occurs to produce the higher energy charge-separated state (1˙+/TTF-C4P/Li+@C60˙), which decays to the ground state with a lifetime of 4.8 μs.

Graphical abstract: Photoinduced electron transfer in a supramolecular triad produced by porphyrin anion-induced electron transfer from tetrathiafulvalene calix[4]pyrrole to Li+@C60

Back to tab navigation

Supplementary files

Article information


Submitted
13 Apr 2015
Accepted
06 May 2015
First published
07 May 2015

This article is Open Access

Chem. Commun., 2015,51, 9789-9792
Article type
Communication
Author version available

Photoinduced electron transfer in a supramolecular triad produced by porphyrin anion-induced electron transfer from tetrathiafulvalene calix[4]pyrrole to Li+@C60

C. M. Davis, K. Ohkubo, A. D. Lammer, D. S. Kim, Y. Kawashima, J. L. Sessler and S. Fukuzumi, Chem. Commun., 2015, 51, 9789
DOI: 10.1039/C5CC03061G

This article is licensed under a Creative Commons Attribution 3.0 Unported Licence. Material from this article can be used in other publications provided that the correct acknowledgement is given with the reproduced material.

Reproduced material should be attributed as follows:

  • For reproduction of material from NJC:
    [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the Centre National de la Recherche Scientifique (CNRS) and the RSC.
  • For reproduction of material from PCCP:
    [Original citation] - Published by the PCCP Owner Societies.
  • For reproduction of material from PPS:
    [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the European Society for Photobiology, the European Photochemistry Association, and RSC.
  • For reproduction of material from all other RSC journals:
    [Original citation] - Published by The Royal Society of Chemistry.

Information about reproducing material from RSC articles with different licences is available on our Permission Requests page.


Social activity

Search articles by author

Spotlight

Advertisements