Visible-light irradiation of photo-labile bromate porphyrin-iron(III) salts gave iron(IV)–oxo porphyrin radical cations (compound I model) or the neutral iron(IV)–oxo porphyrin (compound II model), depending on the electronic structure of porphyrin ligands.
T. Chen, N. Asiri, K. W. Kwong, J. Malone and R. Zhang, Chem. Commun., 2015, 51, 9949 DOI: 10.1039/C5CC02852C
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