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Issue 37, 2015
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Preparation, structure, and versatile reactivity of pseudocyclic benziodoxole triflate, new hypervalent iodine reagent

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Abstract

A new pseudocyclic triflate derivative of benziodoxole (IBA–OTf) was prepared and characterized by X-ray analysis. This highly electrophilic reagent readily reacts with various organic substrates to give the corresponding products in good yields. Furthermore, IBA–OTf can be used as a catalyst with m-chloroperoxybenzoic acid as the terminal oxidant.

Graphical abstract: Preparation, structure, and versatile reactivity of pseudocyclic benziodoxole triflate, new hypervalent iodine reagent

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Article information


Submitted
10 Mar 2015
Accepted
01 Apr 2015
First published
01 Apr 2015

Chem. Commun., 2015,51, 7835-7838
Article type
Communication

Preparation, structure, and versatile reactivity of pseudocyclic benziodoxole triflate, new hypervalent iodine reagent

A. Yoshimura, K. C. Nguyen, S. C. Klasen, A. Saito, V. N. Nemykin and V. V. Zhdankin, Chem. Commun., 2015, 51, 7835
DOI: 10.1039/C5CC02009C

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