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Issue 54, 2015
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Acrylate formation from CO2 and ethylene: catalysis with palladium and mechanistic insight

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Abstract

We report the first catalyst based on palladium for the reaction of CO2, alkene and a base to form sodium acrylate and derivatives. A mechanism similar to a previously reported Ni(0)-catalyst is proposed based on stoichiometric in situ NMR experiments, isolated intermediates and a parent palladalactone. Our palladium catalyst was applied to the coupling of CO2 with conjugated alkenes.

Graphical abstract: Acrylate formation from CO2 and ethylene: catalysis with palladium and mechanistic insight

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Supplementary files

Article information


Submitted
06 Mar 2015
Accepted
02 Jun 2015
First published
03 Jun 2015

Chem. Commun., 2015,51, 10907-10909
Article type
Communication
Author version available

Acrylate formation from CO2 and ethylene: catalysis with palladium and mechanistic insight

S. C. E. Stieber, N. Huguet, T. Kageyama, I. Jevtovikj, P. Ariyananda, A. Gordillo, S. A. Schunk, F. Rominger, P. Hofmann and M. Limbach, Chem. Commun., 2015, 51, 10907 DOI: 10.1039/C5CC01932J

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