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Issue 38, 2015
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Mechanochemical reactions studied by in situ Raman spectroscopy: base catalysis in liquid-assisted grinding

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Abstract

In situ Raman spectroscopy was employed to study the course of a mechanochemical nucleophilic substitution on a carbonyl group. We describe evidence of base catalysis, akin to catalysis in solution, achieved by liquid-assisted grinding.

Graphical abstract: Mechanochemical reactions studied by in situ Raman spectroscopy: base catalysis in liquid-assisted grinding

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Article information


Submitted
06 Mar 2015
Accepted
01 Apr 2015
First published
01 Apr 2015

This article is Open Access

Chem. Commun., 2015,51, 8058-8061
Article type
Communication

Mechanochemical reactions studied by in situ Raman spectroscopy: base catalysis in liquid-assisted grinding

M. Tireli, M. Juribašić Kulcsár, N. Cindro, D. Gracin, N. Biliškov, M. Borovina, M. Ćurić, I. Halasz and K. Užarević, Chem. Commun., 2015, 51, 8058
DOI: 10.1039/C5CC01915J

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