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Issue 43, 2015
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Synthesis of radiolabelled aryl azides from diazonium salts: experimental and computational results permit the identification of the preferred mechanism

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Abstract

Experimental and computational studies on the formation of aryl azides from the corresponding diazonium salts support a stepwise mechanism via acyclic zwitterionic intermediates. The low energy barriers associated with both transition structures are compatible with very fast and efficient processes, thus making this method suitable for the chemical synthesis of radiolabelled aryl azides.

Graphical abstract: Synthesis of radiolabelled aryl azides from diazonium salts: experimental and computational results permit the identification of the preferred mechanism

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Publication details

The article was received on 06 Mar 2015, accepted on 17 Apr 2015 and first published on 17 Apr 2015


Article type: Communication
DOI: 10.1039/C5CC01913C
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Citation: Chem. Commun., 2015,51, 8954-8957
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    Synthesis of radiolabelled aryl azides from diazonium salts: experimental and computational results permit the identification of the preferred mechanism

    S. M. Joshi, A. de Cózar, V. Gómez-Vallejo, J. Koziorowski, J. Llop and F. P. Cossío, Chem. Commun., 2015, 51, 8954
    DOI: 10.1039/C5CC01913C

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