An in situ generated cationic zirconium complex stabilized by an n-butylamine-bridged bis(phenolato) ligand has been developed to catalyse hydroamination reactions of secondary amines, which is the first example of group 4 metal based catalysts capable of mediating intermolecular hydroamination reactions of N-aryl/alkyl amines.
Q. Sun, Y. Wang, D. Yuan, Y. Yao and Q. Shen, Chem. Commun., 2015, 51, 7633 DOI: 10.1039/C5CC01780G
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