A tunable decarboxylative alkylation of cinnamic acids with alkanes was developed to form alkenes or ketones under transition metal-free conditions. In the presence of DTBP or DTBP/TBHP, the reaction gave alkenes and ketones respectively via a radical mechanism in moderate to good yields.
J. Ji, P. Liu and P. Sun, Chem. Commun., 2015, 51, 7546 DOI: 10.1039/C5CC01762A
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