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Issue 31, 2015
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Improving photo-controlled living radical polymerization from trithiocarbonates through the use of continuous-flow techniques

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Abstract

Herein, we report simple flow reactor designs that enable photo-controlled living radical polymerization (photo-CRP) from trithiocarbonates (TTCs) with significant enhancements in scalability and reaction rates compared to the analogous batch reactions. We also demonstrate the “on/off” photo-switchability of this reaction under flow conditions.

Graphical abstract: Improving photo-controlled living radical polymerization from trithiocarbonates through the use of continuous-flow techniques

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Article information


Submitted
20 Feb 2015
Accepted
17 Mar 2015
First published
17 Mar 2015

Chem. Commun., 2015,51, 6742-6745
Article type
Communication
Author version available

Improving photo-controlled living radical polymerization from trithiocarbonates through the use of continuous-flow techniques

M. Chen and J. A. Johnson, Chem. Commun., 2015, 51, 6742
DOI: 10.1039/C5CC01562F

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