Issue 34, 2015
From the journal:

Chemical Communications

A rhodium(i)-catalysed formal intramolecular C–C/C–H bond metathesis†

Takanori Matsuda ORCID logo *a  and  Itaru Yuiharaa  

* Corresponding authors

a Department of Applied Chemistry, Tokyo University of Science, 1–3 Kagurazaka, Shinjuku-ku, Tokyo 162-8601, Japan
E-mail: mtd@rs.tus.ac.jp
Fax: +81 3 5261 4631

Abstract

Phenylcyclobutanes underwent skeletal reorganisation in the presence of Wilkinson's catalyst to afford indanes through a cascade process involving chelation-assisted C–C bond cleavage and intramolecular C–H bond cleavage.

Graphical abstract: A rhodium(i)-catalysed formal intramolecular C–C/C–H bond metathesis

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Article information

DOI
https://doi.org/10.1039/C5CC01415H
Article type
Communication
Submitted
17 Feb 2015
Accepted
23 Mar 2015
First published
23 Mar 2015

Chem. Commun., 2015,51, 7393-7396

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A rhodium(I)-catalysed formal intramolecular C–C/C–H bond metathesis

T. Matsuda and I. Yuihara, Chem. Commun., 2015, 51, 7393 DOI: 10.1039/C5CC01415H

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