Palladium catalyzed selective mono-arylation of o-carboranes with aryl iodides has been developed, and a series of B(8)/B(9)-Ar-o-carboranes anchored with active groups have been synthesized with moderate to good yield as well as good selectivity. The mechanism involving PdII catalyzed electrophilic B–H activation was also proposed.
K. Cao, Y. Huang, J. Yang and J. Wu, Chem. Commun., 2015, 51, 7257 DOI: 10.1039/C5CC01331C
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