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Issue 33, 2015
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Visible light promoted carbodifluoroalkylation of allylic alcohols via concomitant 1,2-aryl migration

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Abstract

A novel visible light promoted carbodifluoroalkylation of allylic alcohols is disclosed. A series of difluoro 1,5-dicarbonyl compounds were obtained through a tandem radical addition and 1,2-aryl migration process. Mechanistic analysis indicated that the 1,2-aryl rearrangement proceeded via a radical intermediate.

Graphical abstract: Visible light promoted carbodifluoroalkylation of allylic alcohols via concomitant 1,2-aryl migration

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Article information


Submitted
10 Feb 2015
Accepted
13 Mar 2015
First published
13 Mar 2015

Chem. Commun., 2015,51, 7222-7225
Article type
Communication
Author version available

Visible light promoted carbodifluoroalkylation of allylic alcohols via concomitant 1,2-aryl migration

P. Xu, K. Hu, Z. Gu, Y. Cheng and C. Zhu, Chem. Commun., 2015, 51, 7222
DOI: 10.1039/C5CC01189B

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