Issue 27, 2015
From the journal:

Chemical Communications

Surface confined synthesis of porphyrin containing two-dimensional polymers: the effect of rigidity and preferential adsorption of building blocks†

Xiuling Sun,‡a   Lixia Fan,‡a   Xin Zhou,*b   Wei Quan Tian,b   Zongxia Guo,*c   Zhibo Li,c   Xiaokang Lid  and  Shengbin Lei*a  

* Corresponding authors

a State Key Laboratory of Robotics and System, Harbin Institute of Technology, Harbin, China
E-mail: leisb@hit.ed.cn

b State Key Laboratory of Urban Water Resource and Environment, Institute of Theoretical and Simulational Chemistry, Academy of Fundamental and Interdisciplinary Science, Harbin Institute of Technology, Harbin, China
E-mail: zhoux@hit.edu.cn

c School of Polymer Science and Engineering, Qingdao University of Science and Technology, Qingdao 266042, China
E-mail: zxguo@qust.edu.cn

d Key Laboratory of Organo-pharmaceutical Chemistry, Gannan Normal University, Ganzhou, Jiangxi 34100, P. R. China

Abstract

We have designed and synthesized two porphyrin containing two-dimensional (2D) polymers based on the imine linkage. Both the 2D polymers are revealed to be 2D organic semiconductors with band gaps of around 1 eV. STM characterization reveals that the rigidity and affinity of building blocks to the surface has essential effects on the topology of the 2D polymers.

Graphical abstract: Surface confined synthesis of porphyrin containing two-dimensional polymers: the effect of rigidity and preferential adsorption of building blocks

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Article information

DOI
https://doi.org/10.1039/C5CC00659G
Article type
Communication
Submitted
23 Jan 2015
Accepted
20 Feb 2015
First published
23 Feb 2015

Chem. Commun., 2015,51, 5864-5867

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Surface confined synthesis of porphyrin containing two-dimensional polymers: the effect of rigidity and preferential adsorption of building blocks

X. Sun, L. Fan, X. Zhou, W. Q. Tian, Z. Guo, Z. Li, X. Li and S. Lei, Chem. Commun., 2015, 51, 5864 DOI: 10.1039/C5CC00659G

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