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Issue 24, 2015
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Iron-catalyzed asymmetric hydrosilylation of ketones

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Abstract

A series of iron complexes of chiral iminopyridine-oxazoline (IPO) ligands have been synthesized. The most sterically hindered iron catalyst exhibits excellent activity (up to 99% yield) and high enantioselectivity (up to 93% ee) in asymmetric hydrosilylation of aryl ketones.

Graphical abstract: Iron-catalyzed asymmetric hydrosilylation of ketones

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Article information


Submitted
22 Jan 2015
Accepted
16 Feb 2015
First published
16 Feb 2015

Chem. Commun., 2015,51, 5073-5076
Article type
Communication

Iron-catalyzed asymmetric hydrosilylation of ketones

Z. Zuo, L. Zhang, X. Leng and Z. Huang, Chem. Commun., 2015, 51, 5073
DOI: 10.1039/C5CC00612K

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