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Issue 26, 2015
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Multiple C–H borylation of phenylhydrazones to boron–nitrogen analogues of benzopentalene

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Abstract

One-pot multiple borylation of phenylhydrazones to a series of novel boron–nitrogen analogues of benzopentalene by the cleavage of C–H bonds with PhBBr2 mediated by NEt3 has been established. The resulting BN benzopentalenes feature unique electronic structures and are luminescent both in solution and the solid state.

Graphical abstract: Multiple C–H borylation of phenylhydrazones to boron–nitrogen analogues of benzopentalene

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Supplementary files

Article information


Submitted
17 Jan 2015
Accepted
19 Feb 2015
First published
19 Feb 2015

Chem. Commun., 2015,51, 5732-5734
Article type
Communication
Author version available

Multiple C–H borylation of phenylhydrazones to boron–nitrogen analogues of benzopentalene

C. Ma, J. Zhang, J. Li and C. Cui, Chem. Commun., 2015, 51, 5732
DOI: 10.1039/C5CC00471C

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