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Issue 19, 2015
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Oxidative Heck desymmetrisation of 2,2-disubstituted cyclopentene-1,3-diones

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Abstract

Oxidative Heck couplings have been successfully developed for 2,2-disubstituted cyclopentene-1,3-diones. The direct coupling onto the 2,2-disubstituted cyclopentene-1,3-dione core provides a novel expedient way of enantioselectively desymmetrising all-carbon quaternary centres.

Graphical abstract: Oxidative Heck desymmetrisation of 2,2-disubstituted cyclopentene-1,3-diones

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Article information


Submitted
15 Jan 2015
Accepted
03 Feb 2015
First published
03 Feb 2015

This article is Open Access

Chem. Commun., 2015,51, 4089-4092
Article type
Communication
Author version available

Oxidative Heck desymmetrisation of 2,2-disubstituted cyclopentene-1,3-diones

S. E. Walker, C. J. C. Lamb, N. A. Beattie, P. Nikodemiak and A.-L. Lee, Chem. Commun., 2015, 51, 4089
DOI: 10.1039/C5CC00407A

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