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Issue 44, 2015
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Ion conducting Li2SiO3-coated lithium-rich layered oxide exhibiting high rate capability and low polarization

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Abstract

Lithium-rich Li1.13Ni0.30Mn0.57O2 has been functionally modified with fast Li+-ion conducting Li2SiO3via a facile and novel method, based on the reaction between Ni0.35Mn0.65C2O4·xH2O and Si(OC2H5)4. Due to the unique Li2SiO3 coating layer which greatly improves the Li+ ion diffusion rate, Li2SiO3@Li1.13Ni0.30Mn0.57O2 exhibits outstanding rate capability, cycle stability and low polarization.

Graphical abstract: Ion conducting Li2SiO3-coated lithium-rich layered oxide exhibiting high rate capability and low polarization

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Article information


Submitted
16 Jan 2015
Accepted
01 Apr 2015
First published
01 Apr 2015

Chem. Commun., 2015,51, 9093-9096
Article type
Communication

Ion conducting Li2SiO3-coated lithium-rich layered oxide exhibiting high rate capability and low polarization

E. Zhao, X. Liu, H. Zhao, X. Xiao and Z. Hu, Chem. Commun., 2015, 51, 9093
DOI: 10.1039/C5CC00383K

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