Issue 35, 2015
From the journal:

Chemical Communications

Polymeric catenanes synthesized via “click” chemistry and atom transfer radical coupling†

Ajaykumar Bunha,a   Peng-Fei Cao,a   Joey Mangadlao,a   Fei-Mo Shi,a   Edward Foster,a   Katrina Pangilinana  and  Rigoberto Advincula*a  

* Corresponding authors

a Department of Macromolecular Science and Engineering, Case Western Reserve University, Cleveland, Ohio 44106, USA
E-mail: rca41@case.edu
Fax: +1-216-368-4202
Tel: +1-216-368-4566

Abstract

A novel route for the synthesis of polymeric catenanes was demonstrated by grafting an alkyne functionalized polymer onto a supramolecularly templated azide terminated ligand followed by ring closure via atom transfer radical coupling (ATRC). The polymeric catenane was characterized via GPC and AFM imaging.

Graphical abstract: Polymeric catenanes synthesized via “click” chemistry and atom transfer radical coupling

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Article information

DOI
https://doi.org/10.1039/C5CC00373C
Article type
Communication
Submitted
14 Jan 2015
Accepted
17 Mar 2015
First published
17 Mar 2015

Chem. Commun., 2015,51, 7528-7531

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Polymeric catenanes synthesized via “click” chemistry and atom transfer radical coupling

A. Bunha, P. Cao, J. Mangadlao, F. Shi, E. Foster, K. Pangilinan and R. Advincula, Chem. Commun., 2015, 51, 7528 DOI: 10.1039/C5CC00373C

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