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Abstract | Cited by

Reaction of a Li/Cl phosphinidenoid complex with N,N′-dialkyl carbodiimides yielded the novel 3-imino-azaphosphiridine complexes; reaction with water led selectively to the first stable valence isomer of an oxaphosphirane complex.

Graphical abstract: Going for strain: synthesis of the first 3-imino-azaphosphiridine complexes and their conversion into oxaphosphirane complex valence isomers

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