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Issue 16, 2015
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Versatile polyiodopyrazoles: synthesis and biocidal promise

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Abstract

An efficient route to polyiodopyrazoles, 3,4,5-triiodopyrazole (1), 1-methyl-3,4,5-triiodopyrazole (2) and 1-diiodomethyl-3,4,5-triiodopyrazole (3), opens the door to prospective biocides. Nitration of 1 and 2 gives the previously inaccessible compounds, 3,4-dinitro-5-iodopyrazole (4), and 3,4-dinitro-5-iodo-1-methylpyrazole (5), respectively. These synthetic pathways will open many fronts for pyrazole chemistry.

Graphical abstract: Versatile polyiodopyrazoles: synthesis and biocidal promise

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Publication details

The article was received on 06 Dec 2014, accepted on 14 Jan 2015 and first published on 15 Jan 2015


Article type: Communication
DOI: 10.1039/C4CC09775K
Chem. Commun., 2015,51, 3438-3441

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    Versatile polyiodopyrazoles: synthesis and biocidal promise

    D. Chand and J. M. Shreeve, Chem. Commun., 2015, 51, 3438
    DOI: 10.1039/C4CC09775K

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