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Issue 18, 2015
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Bonding situation in Be[N(SiMe3)2]2 – an experimental and computational study

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Abstract

The solid state structure of Be[N(SiMe3)2]2 (1) was determined by in situ crystallisation and the bonding situation investigated by quantum chemical calculations. The Be–N bond is predominantly ionic, but some evidence for the presence of a partial Be–N double bond character was found.

Graphical abstract: Bonding situation in Be[N(SiMe3)2]2 – an experimental and computational study

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Article information


Submitted
05 Dec 2014
Accepted
29 Jan 2015
First published
30 Jan 2015

This article is Open Access

Chem. Commun., 2015,51, 3889-3891
Article type
Communication

Bonding situation in Be[N(SiMe3)2]2 – an experimental and computational study

D. Naglav, A. Neumann, D. Bläser, C. Wölper, R. Haack, G. Jansen and S. Schulz, Chem. Commun., 2015, 51, 3889
DOI: 10.1039/C4CC09732G

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