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Issue 28, 2015
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Origin of SMM behaviour in an asymmetric Er(iii) Schiff base complex: a combined experimental and theoretical study

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Abstract

An asymmetric erbium(III) Schiff base complex [Er(HL)2(NO3)3] was synthesized which shows SMM behaviour with an Ueff of 5.2 K. Dipolar interaction in 1 significantly reduced upon dilution which increases the barrier height to 51.5 K. Ab initio calculations were performed to shed light on the mechanism of magnetization relaxation.

Graphical abstract: Origin of SMM behaviour in an asymmetric Er(iii) Schiff base complex: a combined experimental and theoretical study

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Article information


Submitted
28 Nov 2014
Accepted
14 Feb 2015
First published
16 Feb 2015

Chem. Commun., 2015,51, 6137-6140
Article type
Communication
Author version available

Origin of SMM behaviour in an asymmetric Er(III) Schiff base complex: a combined experimental and theoretical study

C. Das, A. Upadhyay, S. Vaidya, S. K. Singh, G. Rajaraman and M. Shanmugam, Chem. Commun., 2015, 51, 6137
DOI: 10.1039/C4CC09523E

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