Two new perylene bisimide (PBI) derivatives possessing crown ether receptors at the 1,7 bay-positions and solubilizing ionic imide substituents were synthesized and their self-assembly properties in the presence of different metal ions were studied, revealing highly selective barium ion templated self-assembly of 15-crown-5 functionalized PBI into H-type dimer aggregates.
A. Weißenstein and F. Würthner, Chem. Commun., 2015, 51, 3415 DOI: 10.1039/C4CC09443C
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