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Issue 7, 2015
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An IrIV-containing polyoxometalate

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[HIrIVW6O24]7−, representing the first Ir-containing Anderson–Evans-type polyanion and the first structurally characterized IrIV-based polyoxometalate, has been isolated as its hydrated sodium salt and characterized by single-crystal X-ray diffraction, mass spectrometry, and IR, UV-Vis and EPR spectroscopy. Cyclic voltammetry indicates that the IrIV ions in [HIrW6O24]7− can undergo reversible one-electron reduction and oxidation, resulting in IrIII and IrV derivatives.

Graphical abstract: An IrIV-containing polyoxometalate

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The article was received on 20 Nov 2014, accepted on 28 Nov 2014 and first published on 28 Nov 2014

Article type: Communication
DOI: 10.1039/C4CC09271F
Citation: Chem. Commun., 2015,51, 1222-1225
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    An IrIV-containing polyoxometalate

    S. A. Adonin, N. V. Izarova, C. Besson, P. A. Abramov, B. Santiago-Schübel, P. Kögerler, V. P. Fedin and M. N. Sokolov, Chem. Commun., 2015, 51, 1222
    DOI: 10.1039/C4CC09271F

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