Issue 25, 2015
From the journal:

Chemical Communications

Electrochemical hydrogenation of a homogeneous nickel complex to form a surface adsorbed hydrogen-evolving species†

Daniel J. Martin,a   Brian D. McCarthy,a   Carrie L. Donleyb  and  Jillian L. Dempsey*a  

* Corresponding authors

a Department of Chemistry, University of North Carolina, Chapel Hill, North Carolina 27599-3290, USA
E-mail: dempseyj@email.unc.edu

b Chapel Hill Analytical and Nanofabrication Laboratory, Department of Applied Physical Sciences, University of North Carolina, Chapel Hill, North Carolina 27599-3216, USA

Abstract

A Ni(II) complex degrades electrochemically in the presence of acid in acetonitrile to form an electrode adsorbed film that catalytically evolves hydrogen. Comparison with a similar compound permitted investigation of the degradation mechanism.

Graphical abstract: Electrochemical hydrogenation of a homogeneous nickel complex to form a surface adsorbed hydrogen-evolving species

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Article information

DOI
https://doi.org/10.1039/C4CC08662G
Article type
Communication
Submitted
31 Oct 2014
Accepted
24 Nov 2014
First published
04 Dec 2014
This article is Open Access
Creative Commons BY-NC license

Chem. Commun., 2015,51, 5290-5293

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Electrochemical hydrogenation of a homogeneous nickel complex to form a surface adsorbed hydrogen-evolving species

D. J. Martin, B. D. McCarthy, C. L. Donley and J. L. Dempsey, Chem. Commun., 2015, 51, 5290 DOI: 10.1039/C4CC08662G

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