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Issue 15, 2015
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On-surface self-organization of a robust metal–organic cluster based on copper(i) with chloride and organosulphur ligands

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Abstract

Direct sublimation of a Cu4Cl4 metal–organic cluster on Cu(110) under ultra-high vacuum allows the formation of ultra-large well-organized metal–organic supramolecular wires. Our results show that the large monomers assemble with each other by π–π interactions connecting dipyrimidine units and are stabilized by the surface.

Graphical abstract: On-surface self-organization of a robust metal–organic cluster based on copper(i) with chloride and organosulphur ligands

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Article information


Submitted
27 Oct 2014
Accepted
09 Jan 2015
First published
12 Jan 2015

Chem. Commun., 2015,51, 3243-3246
Article type
Communication
Author version available

On-surface self-organization of a robust metal–organic cluster based on copper(I) with chloride and organosulphur ligands

G. Otero-Irurueta, I. Hernández-Rodríguez, J. I. Martínez, R. Palacios-Rivera, F. J. Palomares, M. F. López, A. I. Gallego, S. Delgado, F. Zamora, J. Méndez and J. A. Martín-Gago, Chem. Commun., 2015, 51, 3243
DOI: 10.1039/C4CC08471C

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