Issue 6, 2015
From the journal:

Chemical Communications

Hydrogen bond distinction and activation upon catalytic etherification of hydroxyl compounds†

Penghua Che,ab   Fang Lu,*a   Xin Nie,a   Yizheng Huang,a   Yanliang Yang,a   Feng Wanga  and  Jie Xu*a  

* Corresponding authors

a State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Chinese Academy of Sciences, Dalian National Laboratory for Clean Energy, Dalian 116023, P. R. China
E-mail: xujie@dicp.ac.cn, lufang@dicp.ac.cn
Fax: +86-411-8437-9245
Tel: +86-411-8437-9245

b University of Chinese Academy of Sciences, Beijing 100049, P. R. China

Abstract

An excellent linear correlation between ln δ (OH chemical shift) and 1/T (temperature) is discovered for the first time for hydroxyl compounds. The derived slope (A) provides information as an index not only for distinguishing different types of H-bonds, but also for predicting their reactivities. This finding can be extended to other H-bond-containing molecules.

Graphical abstract: Hydrogen bond distinction and activation upon catalytic etherification of hydroxyl compounds

About
Cited by
Related
Download options Please wait...

Supplementary files

Article information

DOI
https://doi.org/10.1039/C4CC08467E
Article type
Communication
Submitted
27 Oct 2014
Accepted
24 Nov 2014
First published
24 Nov 2014

Chem. Commun., 2015,51, 1077-1080

Author version available

Download author version (PDF)

Permissions

Request permissions

Hydrogen bond distinction and activation upon catalytic etherification of hydroxyl compounds

P. Che, F. Lu, X. Nie, Y. Huang, Y. Yang, F. Wang and J. Xu, Chem. Commun., 2015, 51, 1077 DOI: 10.1039/C4CC08467E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements