Jump to main content
Jump to site search

Issue 25, 2015
Previous Article Next Article

Catalytic, highly enantioselective, direct amination of enecarbamates

Author affiliations

Abstract

Amination of enecarbamates with dibenzylazodicarboxylate and oxygenated nucleophiles in the presence of a catalytic amount of chiral phosphoric acid afforded optically active stable precursors of α-hydrazinoimines, which were reduced or oxidized, respectively, to vicinal diamines or α-amino acid precursors with excellent yield and enantioselectivity.

Graphical abstract: Catalytic, highly enantioselective, direct amination of enecarbamates

Back to tab navigation

Supplementary files

Publication details

The article was received on 13 Oct 2014, accepted on 18 Nov 2014 and first published on 21 Nov 2014


Article type: Communication
DOI: 10.1039/C4CC08052A
Author version
available:
Download author version (PDF)
Citation: Chem. Commun., 2015,51, 5383-5386

  •   Request permissions

    Catalytic, highly enantioselective, direct amination of enecarbamates

    A. Dumoulin, C. Lalli, P. Retailleau and G. Masson, Chem. Commun., 2015, 51, 5383
    DOI: 10.1039/C4CC08052A

Search articles by author

Spotlight

Advertisements